Beilstein J. Org. Chem.2023,19, 593–634, doi:10.3762/bjoc.19.44
–Jung vinylsilane reagents 33. Kawamura et al. performed zinc enolate trapping reactions using ligand L10, a chiral quinoline-based N,N,P-ligand (Scheme 8A) [35]. The authors have concluded that the strict control of the amount of organozinc reagent added is essential to avoid side-product formation
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Graphical Abstract
Scheme 1:
General scheme depicting tandem reactions based on an asymmetric conjugate addition followed by an ...
Beilstein J. Org. Chem.2016,12, 1185–1195, doi:10.3762/bjoc.12.114
-leucine.
Keywords: allylic substitution; asymmetric hydrogenation; iridium; N,Pligand; palladium; Introduction
Since their introduction and first successful application in enantioselective palladium-catalyzed allylic substitution in 1993 [1][2][3], chiral phosphinooxazolines (PHOX ligands) have emerged
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Graphical Abstract
Figure 1:
Structural motifs of phospinooxazoline ligands.